Magnetic tape

ABSTRACT

A magnetic tape comprising a substrate having on one side thereof a magnetic layer serving as a recording surface and on the other side thereof a resin layer serving as a non-recording surface, wherein said magnetic tape has a region on the side of the non-recording surface along the longitudinal direction of the tape in which a regular pattern for servo tracking having different optical properties from the other major region of the side of the non-recording surface is to be formed, and said magnetic tape has a thickness of 7 μm or less.

TECHNICAL FIELD

[0001] The present invention relates to magnetic tape capable ofoptically recording servo signals for tracking. More particularly, itrelates to magnetic tape capable of optically recording servo signalsfor tracking on the side opposite to the magnetic recording side.

BACKGROUND ART

[0002] General magnetic tape has a low recording density because of itslow track density. Serpentine type magnetic tape particularly has a lowrecording density. On the other hand, helical scan type magnetic tape,which uses a servo tracking system called automatic track finding (ATF),possesses a higher track density than the serpentine type magnetic tape.

[0003] Servo tracking systems proposed for serpentine type magnetic tapeinclude an embedded servo system, in which servo signals are written onthe same track as the data track on the magnetic recording surface, anda system in which a track exclusive to servo signals is provided on themagnetic recording surface. Japanese Patent Publication No. 82626/95discloses a servo control system particularly useful where the pitch ofdata tracks is as small as several tens of microns, in which a dedicatedtrack for servo information is provided on the magnetic recordingsurface and a plurality of servo reproduction heads are used for readingthe servo signals. According to this technique, however, the number ofserve reproduction heads must be increased as the number of tracksincreases. Otherwise, the number of servo tracks should be increased.Like this, conventional servo tracking systems use the same side ofmagnetic tape as used by data recording, which means that the datarecording area is reduced accordingly. This disadvantage is conspicuousin the servo tracking system of Japanese Patent Publn. No. 82626/95 whena track density is as high as about 30 tracks per mm or even more.

DISCLOSURE OF INVENTION

[0004] Accordingly, an object of the present invention is to provide amagnetic tape which furnishes information for servo tracking withoutlessening the data recording area.

[0005] Another object of the present invention is to provide a magnetictape having an high track density.

[0006] Still another object of the present invention is to provide amagnetic tape which furnishes information for servo tracking whilemaintaining a high S/N ratio.

[0007] Yet another object of the present invention is to provide amagnetic tape having a high recording capacity.

[0008] The inventors of the present invention have found that the aboveobjects are accomplished by a magnetic tape having formed on the sideopposite to the magnetic recording side thereof a layer capable ofoptically recording servo signals for tracking.

[0009] Completed based on the above finding, the present inventionprovides a magnetic tape comprising a substrate having on one sidethereof a magnetic layer serving as a recording surface and on the otherside thereof a resin layer serving as a non-recording surface, whereinthe magnetic tape has a region on the side of the non-recording surfacealong the longitudinal direction of the tape in which a regular patternfor servo tracking having different optical properties from the othermajor region of the side of the non-recording surface is to be formed,and the magnetic tape has a thickness of 7 μm or less.

[0010] The present invention also provides a magnetic tape comprising asubstrate having on one side thereof a magnetic layer serving as arecording surface and on the other side thereof a resin layer serving asa non-recording surface, wherein said magnetic tape has a regularpattern for servo tracking on the side of the non-recording surfacealong the longitudinal direction of the tape which has different opticalproperties from the other major region of the side of the non-recordingsurface, and said magnetic tape has a thickness of 7 μm or less.

[0011] According to the present invention it is provided a magnetic tapewhich furnishes servo information without reducing the data area, amagnetic tape which furnishes information for servo tracking whilemaintaining a high S/N ratio, a magnetic tape which furnishes servoinformation without impairing the properties inherent to a backcoatinglayer, a magnetic tape having an increased track density, and a magnetictape having a high recording capacity.

[0012] In particular, the present invention provides a magnetic tapehaving a metallic thin layer located between the substrate and abackcoating layer, which tape has high stiffness for its thickness assmall as 7 μm or less and thereby easily achieves high recordingcapacity without involving reductions in running properties anddurability.

BRIEF DESCRIPTION OF DRAWINGS

[0013] Various other objects, features and attendant advantages of thepresent invention will be more fully appreciated as the same becomesbetter understood from the following detailed description whenconsidered in connection with the accompanying drawings in which likereference characters designate like or corresponding parts throughoutthe several views and wherein:

[0014]FIG. 1 is a schematic view showing the structure of a firstembodiment of the magnetic tape according to the present invention;

[0015]FIG. 2 schematically illustrates a method for forming acolor-changed pattern by irradiating a backcoating layer with a lightbeam;

[0016]FIG. 3 is an enlarged partial view of the irradiated backcoatinglayer;

[0017]FIG. 4(a), FIG. 4(b), FIG. 4(c) and FIG. 4(d) schematicallyillustrate a method for achieving servo control by push-pull method;

[0018]FIG. 5 shows another color-changed pattern (corresponding to FIG.3);

[0019]FIG. 6 is a schematic view showing the structure of a secondembodiment of the magnetic tape according to the present invention;

[0020]FIG. 7 is a schematic view showing the structure of a thirdembodiment of the magnetic tape according to the present invention;

[0021]FIG. 8 schematically illustrates a method for achieving servocontrol on the third embodiment of the magnetic tape according to thepresent invention;

[0022]FIG. 9 is a schematic view showing the structure of a fourthembodiment of the magnetic tape according to the present invention;

[0023]FIG. 10 is a schematic view showing the structure of a fifthembodiment of the magnetic tape according to the present invention;

[0024]FIG. 11 is an enlarged plane view of servo tracking pattern of themagnetic tape shown in FIG. 10;

[0025]FIG. 12 is a schematic view showing the structure of anotherembodiment of the magnetic tape according to the present invention(corresponding to FIG. 1);

[0026]FIG. 13 is a schematic view showing the structure of anotherembodiment of the magnetic tape according to the present invention(corresponding to FIG. 6);

[0027]FIG. 14 is a schematic view showing the structure of anotherembodiment of the magnetic tape according to the present invention(corresponding to FIG. 7); and

[0028]FIG. 15 is a schematic view showing the structure of anotherembodiment of the magnetic tape according to the present invention(corresponding to FIG. 9).

BEST MODE FOR CARRYING OUT THE INVENTION

[0029] The magnetic tape of the present invention will be described indetail with reference to the preferred embodiments thereof depicted inthe accompanying drawings.

[0030] A magnetic tape 1 shown in FIG. 1 comprises a substrate 2 havingprovided thereon an intermediate layer 3 and a magnetic layer 4 as a toplayer adjoining the intermediate layer 3. The magnetic layer 4 serves asa recording surface. The substrate 2 has on the other side a layer 5containing a coloring matter (hereinafter referred to as acolor-containing layer). The color-containing layer serves as anon-recording surface.

[0031] The term “recording surface” as used herein means a surface usedfor magnetic recording, and the term “non-recording surface” as usedherein means a surface which does not participate in magnetic recording.

[0032] The magnetic tape 1 is for a serpentine recording system, inwhich the magnetic layer 4 contains a plurality of data tracks inparallel with the tape running direction. On use, a head unit having aprescribed number of magnetic heads is moved across the magnetic tape 1,switching among data tracks, to record or reproduce data on theprescribed data track. In order to position each magnetic head on aproper data track by track switching for recording or reproduction,servo tracking is carried out.

[0033] The color-containing layer 5 is an outermost layer on one side ofthe magnetic tape 1. It contains a coloring matter that changes itscolor on being irradiated with light having a prescribed wavelength andtherefore changes its absorbance of light having a prescribedwavelength. The light causing a color change and the light for detectingan absorbance change may have the same or different wavelengths. Theterm “light” as used herein means not only visible light but light ofother wavelength regions. Accordingly, the term “coloring matter” asused herein is intended to include not only substances which show acolor with visible light, i.e., absorb light having a visiblewavelength, but those substances which absorb light of other wavelengthregions, for example, near infrared wavelengths.

[0034] The color-containing layer 5 provided on the side of thenon-recording surface of the magnetic tape 1 is used as a region onwhich a regular pattern for servo tracking having different opticalproperties from the other major region of the side of the non-recordingsurface is to be formed. While not limiting, the optical properties asreferred to herein include the properties as expressed in terms ofreflectance or transmission of light.

[0035] The coloring matter in the color-containing layer 5 changes itscolor on being irradiated with light having a prescribed wavelength fromthe side of the color-containing layer 5 to form a prescribedcolor-changed pattern furnishing servo signals. The method for formingthe color-changed pattern is explained by referring to FIG. 2.

[0036] As shown in FIG. 2, a plurality of laser beams 41 are emitted inparallel from the respective laser light sources 40 aligned atprescribed intervals across the width direction of the magnetic tape 1and illuminate the color-containing layer 5 running in direction A at apredetermined speed. The coloring matter thus irradiated with laserbeams 41 undergoes decomposition by the light energy to change itscolor. The irradiation conditions of the laser beams 41 should becontrolled so as to cause the coloring matter in the color-containinglayer 5 to change its color. The color change of the coloring matterprovides a prescribed color-changed pattern 10 in the color-containinglayer 5 (the color-changed pattern 10 shown in FIG. 2 is not to scale).The degree of the color change is such that can be recognized bymeasuring the intensity of transmitted light, reflected light orphosphorescence. The color-changed pattern obtained in this embodimentis comprised of a plurality of continuous lines of prescribed width inparallel to the longitudinal direction of the magnetic tape 1 asillustrated in FIG. 2. The width w of each line and variation of thedegree of color change in the thickness direction of thecolor-containing layer 5 can be adjusted by controlling the beamdiameter and output power of the laser beams 41. In this embodiment, thebeam diameter is preferably 0.25 to 30 μm, particularly 1 to 25 μm, andthe output power is preferably 1 to 1000 mW, particularly 10 to 100 mW.The wavelength of the laser beams is selected appropriately according tothe kind of the coloring matter so that the coloring matter may show adetectable color change. The color-changed pattern 10 can be formed byuse of an exclusive device before use of the magnetic tape 1 or by useof a recording and reproducing drive equipped with an irradiating meansas shown in FIG. 2.

[0037]FIG. 3 is referred to for going into details of the color-changedpattern thus formed. The color-changed pattern 10 is comprised ofstraight lines having a prescribed width w, arrayed in parallel to eachother in the longitudinal direction of the tape and spaced equally inthe width direction of the tape. While, in general, the color-changedpattern 10 is formed over the whole length of the color-containing layer5 which corresponds to the length of the magnetic layer 4, the area inwhich a color-changed pattern is to be formed is not limited thereto.The color-changed pattern 10 makes an optical contrast with the othernon-irradiated areas of the color-containing layer 5 showing no colorchange. As stated previously, data tracks of the magnetic layer 4 areformed in parallel in the longitudinal direction of the magnetic tape 1similarly to the color-changed pattern 10, but the relative positionalrelationship between the data tracks and the color-changed pattern 10 isnot particularly limited.

[0038] The optical contrast can be made by irradiating the color-changedpattern 10 with light of prescribed wavelength to produce a differencein intensity of transmitted light or reflected light.

[0039] Where the contrast of transmitted light intensity is used forservo control, the intensity of transmitted light is detected andprocessed by an optical servo mechanism, such as push-pull method orthree-beam method, to carry out servo tracking. In using the contrast ofreflected light intensity, the intensity of reflected light is detectedand processed similarly. The optical servo mechanisms, such as push-pullmethod and three-beam method, are techniques commonly employed forachieving optical servo control in various optical disks.

[0040] Servo control based on the contract of transmitted lightintensity by push-pull method is carried out as follows. In FIG. 4(a),magnetic tape having the color-containing layer 5 runs in the directionperpendicular to the surface of the paper. Light is emitted from a lightsource 30, such as a semiconductor laser, which is placed to face thecolor-containing layer 5, condensed through a lens 31 to a prescribedbeam diameter, and enters the color-changed pattern 10 formed in thecolor-containing layer 5. The beam diameter should be somewhat smallerthan the line width of the color-changed pattern. Light transmittedthrough the color-changed pattern 10, the substrate 2 (not shown), theintermediate layer 3 (not shown), and the magnetic layer 4 (not shown)is detected by a light detector 33. The transmitted light, whichcorresponds to the servo signals recorded in the color-changed pattern10, is converted to electrical signals in the light detector 33 and sentto a servo tracking processor 34, where the symmetry of the transmittedlight beam intensity is analyzed. If the beam intensity displaysbilateral symmetry, it means that the center of the beam 35 is on thecenter line of the line width of the color-changed pattern 10 as shownin FIG. 4(b). This state is an “on-track” state, that is, the magnetichead is properly positioned on an aimed data track of the magnetic layer4. If the beam intensity lacks bilateral symmetry, it indicates that thebeam 35 is deviating from the center line to either left or right asshown in FIG. 4(c) or (d). This state is an “off-track” state, that is,the magnetic head is not properly positioned on the aimed data track ofthe magnetic layer. Then the servo tracking processor 34 gives a drive35 of the magnetic head 34 instructions to move the magnetic head 36 toa proper position as shown in FIG. 4(a). As a result, the magnetic head36 is properly positioned by the drive 35 to achieve an “on-track”state. The wavelength of the light used in the serve control is selectedappropriately in conformity with the colors of the coloring matterbefore and after color change.

[0041] The line width w (see FIG. 3) of the color-changed pattern 10 ispreferably 0.25 to 50 μm while somewhat varying with the width of themagnetic tape 1. If the line width w is smaller than 0.25 μm, opticaldetection of the color-changed pattern may be disturbed because it isdifficult to condense the beam to such a small diameter with thestate-of-the-art technique. If the line width w exceeds 50 μm, thedensity of the color-changed pattern 10 decreases where the pattern iscomprised of a large number of lines as illustrated in FIG. 3. Apreferred line width w of the color-changed pattern 10 is 0.25 to 30 μm,particularly 0.8 to 25 μm.

[0042] It is preferred that the pitch p of the color-changed pattern 10,i.e., the pitch of the lines (see FIG. 3) be not less than the width ofthe data track formed on the magnetic layer 4 and be an integralmultiple of the width of the data track.

[0043] Where transmitted light is used for reading servo signals, it ispreferable for the magnetic tape 1 before color change (i.e., beforerecording of the servo signals) to have a transmission of 3% or higher,particularly 5% or higher, at the wavelength of the light to be used forreading the servo signals. A higher transmission is better with noparticular upper limit, but a practical maximum of the transmission ofthe whole magnetic tape 1 would be about 40%, being limited by the lowlight transmitting properties of the magnetic layer 4.

[0044] For achieving precise servo control, it is preferred that thedifference in transmission at the wavelength of incident light used forservo signal reading between the color-changed pattern 10 and the othermajor region of the side of the non-recording surface, i.e., the valuerepresented by equation (1) shown below be 10% or more, particularly 40%or more. $\begin{matrix}{{{Difference}\quad {in}\quad {transmission}\quad (\%)} = {\frac{{T_{M} - T_{O}}}{T_{M}} \times 100}} & (1)\end{matrix}$

[0045] wherein T_(O) represents a transmission (%) of a servo trackingpattern at the wavelength of incident light; and T_(M) represents atransmission (%) of the area other than the servo tracking pattern atthe wavelength of incident light.

[0046] The lines composing the color-changed pattern 10 may be arrangedover the whole width of the magnetic tape 1 at prescribed intervals, ora group of lines spaced at prescribed intervals may be localized in, forexample, the central portion or either one of side portions of the tapein the width direction. There may be two or more groups of lineslocalized in two or more positions of the tape in the width direction.For example, one or more than one groups of lines, which may consist ofthe same or different number of lines, can be arranged on each sideportion of the tape, one or more than one groups of lines, which mayconsist of the same or different number of lines, can be arranged on thecentral portion and one of the side portions of the tape, or one or morethan one groups of lines, which may consist of the same or differentnumber of lines, can be arranged on the central portion and each sideportion of the tape. In any case, the total number of the lines makingup the color-changed pattern 10 is preferably a measure of the number ofthe data tracks of the magnetic layer 4.

[0047] The coloring matter which can be used in the color-containinglayer 5 is not particularly limited as long as it changes its color onbeing irradiated with light having a prescribed wavelength and changesits absorbance of light having a prescribed wavelength. Examples ofpreferred coloring matters include organic coloring matters, such ascyanine dyes, squarylium dyes, chroconium dyes, azulenium dyes,triarylamine dyes, anthraquinone dyes or pigments, metallized azo dyesor pigments, dithiol metal complex dyes, indoaniline metal complex dyes;phthalocyanine pigments, naphthalocyanine pigments, porphyrin pigments,and intramolecular charge transfer complexes. These coloring matters canbe used either individually or as a mixture of two or more thereof.

[0048] Cyanine dyes represented by formula (1) or (2) shown below areparticularly preferred for their satisfactory compatibility with abinder (hereinafter described). These cyanine dyes have an absorption inthe near infrared region.

[0049] wherein R₁ and R₂, which may be the same or different, eachrepresent a hydrocarbon group having 1 to 5 carbon atoms; n and m eachrepresent a number of 1 to 5; and X⁻ represents a monovalent anion.

[0050] The color-containing layer 5 may be formed solely of the coloringmatter but preferably contains a binder so that the color-containinglayer 5 may serve as a backcoating layer which can improve the runningproperties or durability of the magnetic tape 1. The weight ratio of thecoloring matter to the binder, which is subject to variation accordingto the kind of the coloring matter, is preferably from 0.01:100 to10:100, still preferably from 0.05:100 to 5:100.

[0051] Any binder customarily employed in magnetic tape is usable. Forexample, thermoplastic resins, thermosetting resins, reactive resins,and mixtures thereof can be used. Specific examples are vinyl chloridecopolymers or modified vinyl chloride copolymers, copolymers comprisingacrylic acid, methacrylic acid or esters thereof, polyvinyl alcoholcopolymers, acrylonitrile copolymers (rubbery resins), polyester resins,polyurethane resins, epoxy resins, cellulosic resins (e.g.,nitrocellulose, cellulose acetate, cellulose acetate butyrate, celluloseacetate propionate, etc), polyvinyl butyral resins, and polyamideresins. These binders preferably have a number average molecular weightof 2,000 to 200,000. The binder resin can have a polarizing functionalgroup (so-called polar group), such as a hydroxyl group, a carboxylgroup or a salt thereof, a sulfoxyl group or a salt thereof, a phosphogroup or a salt thereof, a nitro group, a nitric ester group, an acetylgroup, a sulfuric ester group or a salt thereof, an epoxy group, anitrile group, a carbonyl group, an amino group, an alkylamino group, analkylammonium salt group, a sulfobetaine structure, a carbobetainestructure, and the like, to have improved dispersing properties forparticulate additives which could be incorporated into thecolor-containing layer 5 (hereinafter described).

[0052] It is preferred for the color-containing layer 5 to contain anantioxidant to improve the stability of the coloring matter. In order tosecure sufficient stability of the coloring matter, the antioxidant ispreferably added in an amount of 0.5 to 20 parts by weight, particularly3 to 10 parts by weight, per 100 parts by weight of the coloring matter.Any antioxidant for organic coloring matters can be used. Specificexamples of suitable antioxidants are bis(4-t-butyl-1,2-dithiophenolate)copper-tetra-n-butylammonium and bis(4-t-butyl-1,2-dithiophenolate)nickel-tetra-n-butylammonium.

[0053] As stated above, the color-containing layer 5 is essentially usedfor recording servo signals for servo tracking but preferably combinesthe functions as a backcoating layer. Such functions include (1) givingsatisfactory running properties, (2) giving antistatic properties, and(3) detecting the beginning of the tape (BOT) or the end of the tape(EOT).

[0054] To perform the function (1), it is preferred for thecolor-containing layer 5 to have a moderate surface roughness. On theother hand, it is preferred for the color-containing layer 5 to be assmooth as possible to prevent the surface profile of thecolor-containing layer 5 from being transferred to the magnetic layer 4when the magnetic tape is rolled up. Taking the balance between theseconflicting requirements into consideration, the color-containing layer5 preferably has an arithmetic mean roughness Ra of 7 to 50 nm,particularly 8 to 30 nm, and a 10 point height parameter Rz of 40 to 250nm, particularly 50 to 200 nm. It is also preferred for thecolor-containing layer 5 to have a coefficient of dynamic friction of0.15 to 0.35.

[0055] The arithmetic mean roughness Ra, defined by the followingequation (i), is measured with a stylus-type profilometer under thefollowing conditions in accordance with JIS-B0601-1994.

[0056] Stylus: diameter: 1.5 to 2.5 μm; curvature: 600

[0057] Contact pressure: 50 to 300 μN

[0058] Cut-off length: 80 μm

[0059] Sampling length: 80 μm

[0060] Assessment length: 400 μm $\begin{matrix}{{Ra} = {\frac{1}{l}{\int_{0}^{l}{{{Y(x)}}{x}}}}} & (i)\end{matrix}$

[0061] wherein Y represents profile data; and l represents an assessmentlength.

[0062] In measuring the surface roughness Ra, a sample is stuck to aslide glass for microscopes which satisfies the requirements specifiedin JIS-R-3502 (e.g., a slide glass produced by MATSUNAMI GLASS K.K. asused in the present invention) with water or ethanol to prepare aspecimen. Existence of excessive water or ethanol will ruin thereproducibility of measurements. Therefore measurement is made after thewater or ethanol is evaporated to some extent and while an interferencefringe can be seen from the back side of the slide glass.

[0063] Measurement of the 10 point height parameter Rz, defined by thefollowing equation (ii), can be made using the same specimen under thesame conditions as for the measurement of Ra in accordance withJIS-B0601-1994. The sampling length l is 80 μm, and the assessmentlength 10 is 400 μm. $\begin{matrix}{{Rz} = \frac{{{Y_{p1} + Y_{p2} + Y_{p3} + Y_{p4} + Y_{p5}}} + {{Y_{v1} + Y_{v2} + Y_{v3} + Y_{v4} + Y_{v5}}}}{5}} & \text{(ii)}\end{matrix}$

[0064] wherein Y_(p1), Y_(p2), Y_(p3), Y_(p4), and Y_(p5) are heights ofthe five highest peaks within the assessment length l; and Y_(v1),Y_(v2), Y_(v3), Y_(v4), and Y_(v5) are height of the five lowest valleyswithin the assessment length l.

[0065] In order for the color-containing layer 5 to have the arithmeticmean roughness Ra and the 10 point height parameter Rz within therespective preferred ranges, it is preferable to incorporate inorganicpowder having an average particle size of 1 to 700 nm into thecolor-containing layer 5. It is particularly preferable to incorporatetwo or more kinds of inorganic powders including particles having anaverage particle size of 1 to 100 nm (hereinafter referred to as powderA) and particles having an average particle size of 50 to 700 nmhereinafter referred to as powder B). A preferred mixing ratio of powderA to powder B ranges from 100:0.1 to 100:20, particularly from 100:0.2to 100:15, by weight. The powders A and B are not particularly limitedin kind as long as their average particle sizes satisfy the aboverespective ranges and include, for example, spherical particles of TiO,TiO₂, α-Fe₂O₃, BaCO₃, BaSO₄, Fe₃O₄, α-Al₂O₃, γ-Al₂O₃, CaCO₃, Cr₂O₃, ZnO,ZnSO₄, α-FeOOH, Mn—Zn ferrite, Ni—Zn ferrite, ZnS, tin oxide,antimony-doped tin oxide (ATO), indium-doped tin oxide (ITO), indiumoxide, carbon black, graphite carbon, SiO₂, and silicone resins having athree-dimensional network structure made up of siloxane bonds with amethyl group bonded to the silicon atom. The powders A and B may be thesame or different in kind.

[0066] Of the above-enumerated inorganic powders, black powder, such ascarbon black, has high light shielding properties. If such black powderis added to the color-containing layer in a large proportion, thecolor-containing layer 5 may not sufficiently transmit light, which isunfavorable where transmitted light is made use of for servo signalreading. In this case, it is recommended not to use such black particlesat all or to use non-black particles as the powder B whose particle sizeis smaller than the thickness of the color-containing layer 5 incombination with such black particles, thereby to achieve the function(1). Powder B, defined to have an average particle size of 50 to 700 nm,preferably has an average particle size of 50 to 500 nm. Powder B ispreferably added in an amount of 0.5 to 150 parts by weight,particularly 1 to 80 parts by weight, especially 2 to 40 parts byweight, per 100 parts by weight of the binder.

[0067] To perform the function (2), it is preferred for thecolor-containing layer 5 to contain an electrically conductive inorganicsubstance (hereinafter simply referred to as conductive substance).Although black particles such as carbon black can be mentioned astypical examples of conductive substances, incorporation of such blackparticles into the color-containing layer 5 in a large proportion maycause the same problem as described above where transmitted light isused for serve signal reading. It would be a preferred embodiment,therefore, not to use such black particles at all or to use non-blackconductive particles as the powder A in combination with such blackparticles, thereby to obtain the function (2). To perform the function(2), the magnetic tape 1 preferably has a surface resistivity of notmore than 1×10⁹ Ω/square on the side of the color-containing layer 5.The lower, the better with no particular lower limit.

[0068] The non-black inorganic conductive particles include particles ofconductive tin oxide, ATO, ITO, and indium oxide. These inorganicconductive substances are advantageous because of their high lighttransmitting properties in the case where transmitted light is utilizedfor servo signal reading. In this connection, especially preferredinorganic conductive particles are tin oxide, ATO, ITO, and indiumoxide. The inorganic conductive particles used as powder A preferablyhave an average particle size of 1 to 100 nm, particularly 2 to 100 nm,especially 5 to 50 nm. The inorganic conductive particles (used aspowder A) is preferably added in an amount of 10 to 800 parts,particularly 30 to 700 parts, especially 50 to 700 parts, by weight per100 parts by weight of the binder.

[0069] In order to obtain an arithmetic mean roughness Ra and a 10 pointheight parameter Rz falling within the respective preferred ranges andto sufficiently obtain the function (2), the total amount of powders Aand B to be added to the color-containing layer 5 preferably ranges from50 to 800 parts by weight, particularly 100 to 700 parts by weight, per100 parts by weight of the binder.

[0070] The function (3) as the backcoating layer can be performed by thecolor-changed pattern 10. EOT or BOT has been detected by a lighttransmission method so that the backcoating layer of conventionalmagnetic tape should contain carbon black. In the present invention, thecolor-containing layer 5 which also serves as a backcoating layer doesnot need to contain carbon black for that detection, which establishesan extreme advantage for the optical serve control using transmittedlight.

[0071] If desired, the color-containing layer 5 can contain additives,such as a lubricant and a hardener.

[0072] Generally useful lubricants include fatty acids and fatty acidesters. Examples of the fatty acid lubricants are caproic acid, caprylicacid, capric acid, lauric acid, myristic acid, palmitic acid, stearicacid, isostearic acid, linolenic acid, oleic acid, elaidic acid, behenicacid, malonic acid, succinic acid, maleic acid, glutaric acid, adipicacid, pimelic acid, azelaic acid, sebacic acid,1,12-dodecanedicarboxylic acid, and octanedicarboxylic acid. Examples ofthe fatty acid ester lubricants are alkyl esters of the above-enumeratedfatty acids having 16 to 46 carbon atoms in total.

[0073] Inorganic acid esters, such as phosphoric esters,fluorine-containing compounds, silicone compounds, and the like are alsouseful as lubricants.

[0074] The lubricants are added in an amount of 0.05 to 15 parts byweight, preferably 0.2 to 10 parts by weight, per 100 parts by weight ofthe binder.

[0075] The hardeners include isocyanate hardeners, exemplified by“CORONATE L” (a trade name, produced by NIPPON POLYURETHANE INDUSTRYCo., Ltd.) and amine hardeners. The hardeners are added in an amount of5 to 40 parts by weight, preferably 5 to 30 parts by weight, per 100parts by weight of the binder.

[0076] If desired, the color-containing layer 5 can further containstabilizers for the coloring matter or sensitizers.

[0077] The color-containing layer 5 is formed by coating the substrate 2with a color-containing coating composition having the above-mentionedcomponents dispersed in a solvent. Examples of suitable solvents includeketones, esters, ethers, aromatic hydrocarbons, chlorinatedhydrocarbons, and cellosolve solvents. The solvent is preferably used insuch an amount that the coating composition may have a solids content of10 to 50% by weight, particularly 20 to 40% by weight.

[0078] The thickness of the color-containing layer 5, formed by applyingthe color-containing coating composition, is preferably 0.1 to 2.0 μm,still preferably 0.2 to 1.5 μm, taking into consideration thetransmission of the color-changed pattern 10 and the thickness balancewith the magnetic layer 4 and the intermediate layer 3.

[0079] The color-containing layer 5 of the magnetic tape 1 according tothis embodiment has a color-changed pattern 10 of a plurality of linesalong the longitudinal direction of the magnetic tape 1 as shown in FIG.3. The pattern of a plurality of lines can be replaced by a singlestraight line along the longitudinal direction of the tape 1. Thepattern can be a single or a plurality of sine curves along thelongitudinal direction of the tape 1. Further, the pattern 10 can becomprised of discontinuous pieces of lines along the longitudinaldirection of the tape 1 as shown in FIG. 5.

[0080] The color-changed pattern 10 shown in FIG. 5 is made up of arepetition of pairs of a piece 10 a angled at Θ° with the longitudinaldirection of the magnetic tape 1 and a piece 10 b angled at −Θ°, thepieces 10 a and 10 b alternating with each other in the longitudinaldirection of the tape 1. The angle Θ has an influence on the precisionof positioning by servo tracking. A preferred angle Θ for securingsufficient precision of positioning is 5 to 85°, particularly 10 to 30°.The lengths of the pieces 10 a and the pieces 10 b may the same ordifferent but are preferably the same. A preferred length of the pieces10 a and 10 b is 5 to 140 mm, particularly 5 to 80 mm. The spacing gbetween the piece 10 a and the piece 10 b making each pair is preferablyas narrow as possible. The servo signals of the color-changed pattern 10shown in FIG. 5 can be read in the same manner as for the pattern 10shown in FIG. 3.

[0081] The second to fifth embodiments of the magnetic tape according tothe present invention will be illustrated with reference to FIGS. 6through 11, wherein FIG. 6, which corresponds to FIG. 1 of the firstembodiment, schematically shows the structure of the second embodiment;FIG. 7, which corresponds to FIG. 1 of the first embodiment,schematically shows the structure of the third embodiment; FIG. 8schematically illustrates a method for obtaining servo information fromthe third embodiment, corresponding to FIG. 4 for the first embodiment;FIG. 9 schematically shows the structure of the fourth embodiment,corresponding to FIG. 7 of the third embodiment; FIG. 10 schematicallyshows the structure of the fifth embodiment; and FIG. 11 is a plane viewof the servo tracking pattern of the magnetic tape shown in FIG. 10. Thesecond to fifth embodiments will be explained only with regard todifferences from the first embodiment. As for the same details as withthe first embodiment, while not noted particularly, the descriptionsgiven to the first embodiment apply appropriately. The same numericalreferences as used in FIGS. 1 through 5 are used for the same elementsin FIGS. 6 to 11.

[0082] Similarly to the first embodiment, the magnetic tape 1 accordingto the second embodiment shown in FIG. 6 has a color-changed patternaffording servo information on its color-containing layer 5 before use.When the magnetic tape 1 is first used, the color-changed pattern isirradiated from one side of the tape 1 with light having a prescribedwavelength, and the transmitted light is detected from the other side.Thus the recorded servo signals are read as contrast of transmittedlight intensity. The difference of the second embodiment from the firstone resides in that the color-containing layer of the first embodimentcombines the function as a backcoating layer, whereas the magnetic tape1 of the second embodiment has a backcoating layer 6 as an outermostlayer independently of the color-containing layer 5. Accordingly, thefunction for recording and reading servo signals and the function as abackcoating layer are separately performed by the respectively designedlayers, which is advantageous in that the freedom of design of themagnetic tape 1 is increased over the first embodiment.

[0083] The color-containing layer 5 used in the second embodimentpreferably consists solely of a coloring matter or comprises othercomponents in addition to the coloring matter.

[0084] The color-containing layer 5 consisting solely of the coloringmatter can be formed by, for example, the following methods (1) to (3).

[0085] (1) A thin film formation processing, such as chemical vapordeposition (CVD) or physical vapor deposition (PVD).

[0086] (2) A method comprising coating the substrate 2 with a solutionof the coloring matter in a solvent which can, if desired, contain asurface active agent.

[0087] (3) A method comprising co-extruding the substrate 2 with asolution of the coloring matter in a polymer or a polymer emulsion.

[0088] Where the color-containing layer 5 comprises the coloring matterand other components, the other components include a binder, inorganicpowder, a lubricant, and the like that could be incorporated into thecolor-containing layer of the first embodiment. With regard to thedetails of these components and their amounts to be added, refer to thefirst embodiment. In particular, the above-described powders A and B canbe incorporated to impart antistatic properties to the color-containinglayer 5. In addition, the incorporation of the powders A and B preventsdisturbances of the interface between the color-containing layer 5 andthe backcoating layer 6 when these two layers are formed by simultaneouscoating in a wet-on-wet system, which will be described later in detail.The color-containing layer 5 comprising these components is formed bycoating the substrate with a color-containing coating compositionprepared by dispersing these components in a solvent. As to the detailsof the color-containing coating composition, the descriptions given tothe first embodiment apply appropriately.

[0089] Because the color-containing layer 5 has no function as abackcoating layer, its thickness may be smaller than that required inthe first embodiment. A preferred thickness is 30 to 200 nm,particularly 50 to 150 nm.

[0090] In order for the backcoating layer 6 to perform its own essentialfunctions, it is preferred for this layer to contain a binder, inorganicpowder (particularly the powders A and B), a lubricant, a hardener, andthe like. As to the details of these components, refer to the firstembodiment. The inorganic powder is preferably used in an amount of 50to 800 parts by weight, particularly 70 to 700 parts by weight, per 100parts by weight of the binder. The lubricant is preferably used in anamount of 0 to 20 parts by weight, particularly 0 to 10 parts by weight,per 100 parts by weight of the binder. The hardener is preferably usedin an amount of 0 to 40 parts by weight, particularly 5 to 30 parts byweight, per 100 parts by weight of the binder.

[0091] Similarly to the first embodiment, it is preferred for adjustingthe light transmission of the magnetic tape as a whole within theabove-described preferred range that the inorganic powder added to thebackcoating layer 6, especially conductive powder, have lighttransmitting properties. Accordingly, it is preferred for the inorganicpowder to have a non-black color and have a small particle size withinan appropriate range. Specifically, the inorganic powder preferably hasa particle size of 1 to 100 nm, particularly 2 to 100 nm, especially 5to 50 nm. In order to further improve the running properties of thebackcoating layer 6, such small particles can be used in combinationwith inorganic powder having a particle size of 50 to 700 nm (e.g., thepowder B).

[0092] The backcoating layer 6 can be formed by coating thecolor-containing layer 5 with a backcoating composition having theabove-described components dispersed in a solvent. Where thecolor-containing layer 6 is formed by applying a coating compositioncontaining the coloring matter dissolved in a solvent (the coatingcomposition used in the method (2) described above) or theabove-described color-containing coating composition comprising thecoloring matter, the binder, and carbon black, etc., such acolor-containing composition and the backcoating composition can beapplied either by successive coating or simultaneous coating. Notingthat the successive coating method has lower productivity and entertainsa fear of the coloring matter's dissolving out of the color-containinglayer 5 and mixing with the backcoating composition, preferred is thesimultaneous coating method according to a wet-on-wet system, whichachieves higher productivity and is free from such a fear.

[0093] The backcoating layer 6 preferably has a thickness of 0.1 to 1.0μm, particularly 0.2 to 1.0 μm, from the viewpoint of sufficientmanifestation of the running properties and durability of the magnetictape 1 and the balance with the total thickness of the intermediatelayer 3 and the magnetic layer 4 formed on the side of the recordingsurface.

[0094] The magnetic tape 1 of the third embodiment shown in FIG. 7 has acolor-changed pattern affording servo signals on its color-containinglayer 5 before use similarly to the first embodiment. The differencefrom the first embodiment lies in that a metallic thin layer(s) 7 and/or8 is/are provided between the substrate 2 (e.g., a plastic film) and thecolor-containing layer 5 and/or between the substrate 2 and theintermediate layer 3 and that the servo signals are read by irradiatingthe side of the color-containing layer of the magnetic tape 1 with lightof prescribed wavelength and then detecting the intensity of lightreflected on the metallic layer. In other words, in the first embodimentservo control is achieved through detection of transmitted light whilein the third embodiment servo signals are read from the reflected light,using a composite of the substrate 2 (plastic film) and the metallicthin layer(s) as a substrate. Either one of the metallic thin layers 7and 8, particularly the layer 7 suffices as a light reflecting layer.

[0095] The servo control mechanism of the third embodiment isillustrated in FIG. 8 corresponding to FIG. 4(a) for the firstembodiment, in which the intensity of the reflected light is detected tocarry out servo tracking. In FIG. 8, the intermediate layer 3 and themagnetic layer 4 of the magnetic tape shown in FIG. 7 are not shown.

[0096] The servo control shown in FIG. 8 is carried out by push-pullmethod similarly to that shown in FIG. 4. In FIG. 8, magnetic tape runsin the direction perpendicular to the surface of the paper. Light isemitted from a light source 30, such as a semiconductor laser, which isplaced to face the color-containing layer 5, condensed through a lens 31to a prescribed beam diameter, passes through a half mirror 37, andenters the color-changed pattern 10 formed in the color-containing layer5. The beam diameter should be somewhat smaller than the line width ofthe color-changed pattern 10. The light transmitted through thecolor-changed pattern 10 is reflected on the metallic thin layer 7 andadvances in the direction opposite to the incidence direction. Thereflected light is reflected on the half mirror 37, turning itsdirection, and enters the light detector 33, where the intensity of thereflected light is detected. The detected reflected light, whichcorresponds to the servo signals recorded in the color-changed pattern10, is converted to electrical signals in the detector 33 and then sentto the servo tracking processor 34, where the signals are processed inthe same manner as in the servo control system of FIG. 4. Thedescriptions given to the system of FIG. 4 apply accordingly.

[0097] Materials having a high reflectance, such as Au, Al, Ag, andalloys based on these metals, are preferably used for the metallic thinlayers 7 and 8. The materials making the metallic thin layers 7 and 8may be the same or different.

[0098] Both metallic thin layers 7 and 8 are preferably formed by knownvacuum thin film processing. Metallic thin layers thus formed exhibitextremely high anticorrosion to provide magnetic tape with excellentstorage durability. Vacuum thin film processing is selected according tothe material forming the layers 7 or 8 from among vacuum deposition,sputtering, ion plating, and the like.

[0099] The metallic thin layers 7 and 8 each have a thickness enough toreflect the incident light sufficiently. Such a thickness is preferably0.01 to 1 μm, still preferably 0.02 to 0.7 μm. The two layers may havethe same or different thicknesses.

[0100] The side of the color-containing layer 5 of the magnetic tape 1according to the third embodiment preferably has a reflectance of atleast 5%, particularly 10% or more, especially 15% or more, at thewavelength of the light to be used for servo signal reading, before theservo signals are recorded. Higher reflectances are better with noparticular upper limit, but a practical maximum would be about 70%.

[0101] For achieving precise servo control, it is preferred that thedifference in reflectance at the wavelength of incident light used forservo signal reading between the color-changed pattern 10 and the otherarea of the non-recording surface, i.e., the value represented byequation (2) shown below be 10% or more, particularly 40% or more.$\begin{matrix}{{{Difference}\quad {in}\quad {reflectance}\quad (\%)} = {\frac{{R_{M} - R_{O}}}{R_{M}} \times 100}} & (2)\end{matrix}$

[0102] wherein R_(O) represents a reflectance (%) of a servo trackingpattern at the wavelength of incident light; and R_(M) represents areflectance (%) of the area other than the servo tracking pattern at thewavelength of incident light.

[0103] Where the magnetic tape 1 has the metallic thin layer 7, thelayer 7 combines two functions; it acts as a reflective film and alsoserves for static prevention. That is, the color-containing layer 5 ofthe third embodiment does not need to contain carbon black or any otherconductive inorganic particles as an antistatic agent unlike the firstembodiment. It follows that the color-containing layer 5 has a highertransmission than that used in the first embodiment thereby providingreflected light with higher intensity, which enhances the precision ofservo control.

[0104] The magnetic tape 1 according to the fourth embodiment shown inFIG. 9 has a metallic thin layer(s) 7 and/or 8 between the substrate 2and the color-containing layer 5 and/or between the substrate 2 and theintermediate layer 3 so that the servo information can be obtained fromthe reflected light in the same manner as in the third embodiment. Thedifference from the third embodiment consists in that thecolor-containing layer of the third embodiment combines the function asa backcoating layer, whereas the magnetic tape 1 of the fourthembodiment has a backcoating layer 6 as an outermost layer independentlyof the color-containing layer 5. The color-containing layer 5 and thebackcoating layer 6 of the fourth embodiment are structurally the sameas those of the second embodiment. That is, the magnetic tape 1 of thefourth embodiment has a combination of the color-containing layer 5 andthe backcoating layer 6 according to the second embodiment and themetallic thin layers 7 and 8 according to the third embodiment.Accordingly, the detailed descriptions given to the second and thirdembodiments with respect to these elements apply here.

[0105] In the fourth embodiment, since the functions for recording andreading servo signals and as a backcoating layer are separately carriedout by the respectively designed layers similarly to the secondembodiment, the magnetic tape 1 has increased freedom of design over thefirst embodiment. Further, since the metallic thin layer 7 combines thefunctions as a reflective layer and for static prevention, thecolor-containing layer 5 or the backcoating layer 6 does not need tocontain carbon black or any other conductive inorganic particles as anantistatic agent. It follows that both the color-containing layer 5 andthe backcoating layer 6 have a higher transmission than those used inthe second embodiment thereby providing reflected light with higherintensity, which enhances the precision of servo control. Similarly tothe third embodiment, the side of the color-containing layer 5 of themagnetic tape 1 according to the fourth embodiment preferably has areflectance of at least 5%, particularly 10% or more, especially 15% ormore, at the wavelength of the light to be used for servo signal readingbefore the servo signals are recorded. The change in reflectance asdefined above is preferably 10% or more, particularly 40% or more,similarly to the third embodiment.

[0106] The magnetic tape 1 according to the fifth embodiment shown inFIG. 10 has on the side of the non-recording surface thereof a thin film9 of a metal or an alloy having a low melting point (hereinafterreferred to as a metallic thin layer) and a backcoating layer 6 as aresin layer adjoining the metallic thin layer 9.

[0107] A servo tracking pattern can be formed in the metallic thin layer9 to exhibit optical properties different from the other major region ofthe side of the non-recording surface. Such a pattern can be formed by,for example, irradiating the metallic thin layer 9 with a laser beamcorresponding to servo signals while moving the magnetic tape 1 at aprescribed speed. The irradiated metal or alloy of the metallic thinlayer 9 fuses to make depressions 9′ (see FIG. 10) of prescribed depthat regular intervals along the longitudinal direction of the tape. Theregularly spaced depressions 9′ work as the pattern. The metallic thinlayer 9 can be irradiated from either side of the non-recording surfaceor the side of the recording surface but is preferably irradiated fromthe side of the non-recording surface for efficient pattern formation.

[0108] In order to form the servo tracking pattern with which preciseservo control can be carried out, the laser beam for pattern formationpreferably has a diameter of 0.1 to 30 μm, particularly 1 to 10 μm. Theoutput power of the laser beam is decided so as to cause the metal oralloy constituting the metallic thin layer 9 to fuse sufficientlywithout damaging the other layers constituting the magnetic tape 1 andthe substrate 2. Such an output power preferably ranges from 1 to 50 mW,particularly 3 to 25 mW, per incident beam. Short pulses of a highoutput laser beam of about 1 to 100 W can also be used. The wavelengthof the laser beam is preferably 0.3 to 1.3 μm, particularly 0.5 to 0.8μm, from the standpoint of the light absorption of the metal or alloy.

[0109] As shown in FIG. 11, the plane view of the servo tracking patternof the fifth embodiment is a single dotted line located on thecenterline of the width direction of the tape. Such a pattern assuresimproved sensitivity in servo signal reading. The depression 9′preferably has a width W of 0.1 to 30 μm, particularly 1 to 20 μm, forobtaining precise servo control and minimizing the thermal influence onthe substrate 2 in pattern formation. The length L of each depression 9′(see FIG. 10) is preferably 1 to 100 μm, particularly 10 to 50 μm, toassure servo signal detection. The distance P between every adjacentdepressions 9′ is preferably 2 to 100 μm, particularly 50 to 90 μm, forreading the individual depressions 9′ with high sensitivity. The depthof each depression 9′ is preferably at least {fraction (1/3)},particularly at least {fraction (2/3)}, of the thickness of the metallicthin layer 9 up to the whole thickness of the metallic thin layer 9. Inthis embodiment shown in FIG. 11, the depressions 9′ are formed over thewhole thickness of the metallic thin layer 9. While in FIG. 10 thedepressions 9′ are depicted as hollow parts for convenience' sake, theyare in fact filled with the substrate 2 and/or the backcoating layer 6.Since the metallic thin layer 9 is considerably thinner than thebackcoating layer 6, filling of the depressions 9 with the backcoatinglayer 6 does not result in depressions on the surface of the backcoatinglayer 6. If any depressions occur on the surface of the backcoatinglayer 6, reduction in surface properties of the backcoating layer 6 dueto the depressions would be negligible. Further, the influence of thedepressions 9′ on the surface of the backcoating layer 6 could beexcluded by controlling the surface smoothness (surface roughness Ra and10 point height parameter Rz) of the backcoating layer 6 as previouslydescribed.

[0110] For servo signal reading, light having a wavelength of 0.3 to 1.3μm, particularly 0.5 to 0.8 μm, is preferably used in view of thewavelength dependence of the reflectance or absorbance of the metal oralloy.

[0111] The metal or alloy which constitutes the metallic thin layer 9 isselected from those fusible with the quantity of radiation heat thatdoes not damage the other layers making up the magnetic tape 1 and thesubstrate 2, such as low-melting metals or alloys having a melting pointof 500° C. or below. Examples of such metals or alloys include indium,tin, lead, zinc, gallium, selenium, rubidium, cadmium, tellurium,cesium, thallium, bismuth, polonium, astatine, lithium, sodium,potassium, a silver-indium alloy having an indium content of about 25%or more, and a silver-bismuth alloy having a bismuth content of severalpercents or more. In particular, indium, tin, lead and zinc arepreferred for their optical characteristics, such as absorbance, andchemical stability.

[0112] The metallic thin layer 9 can be formed by known vacuum thin filmprocessing such as vacuum deposition, sputtering, and chemical vapordeposition. In order to induce a sufficiently large difference inreflectance or transmission, which is as defined above, while minimizingthe influence of the depressions 9′ on the surface properties of thenon-recording surface, the thickness of the metallic thin layer 9preferably ranges from 5 to 500 nm, particularly from 50 to 300 nm.

[0113] General items concerning the magnetic tape according to thepresent invention are now described. Unless particularly noted, thefollowing description is common to all the aforesaid embodiments.

[0114] The magnetic layer 4 is formed by applying a magnetic coatingcomposition comprising ferromagnetic powder and a binder. Namely, themagnetic tape 1 is a magnetic tape of coated type.

[0115] The ferromagnetic powder which can be used include acicular,spindle-shaped or tabular particles. Acicular or spindle-shapedferromagnetic powder includes ferromagnetic metal powder consistingmainly of iron and ferromagnetic iron oxide powder, and tabularferromagnetic powder includes ferromagnetic hexagonal ferrite powder.

[0116] More specifically, the ferromagnetic metal powder includes powderhaving a metal content of not less than 50% by weight, 50% by weight ormore of which is Fe. Specific examples of such ferromagnetic metalpowders includes Fe—Co, Fe—Ni, Fe—Al, Fe—Ni—Al, Fe—Co—Ni, Fe—Ni—Al—Zn,and Fe—Al—Si. The acicular or spindle-shaped ferromagnetic metal powderpreferably has a major axis length of 0.03 to 0.2 μm, particularly 0.05to 0.10 μm, with an acicular ratio (major axis length/minor axis length)of 3 to 15, particularly 3 to 10, and a BET specific surface area of 30to 70 m²/g. The acicular or spindle-shaped ferromagnetic metal powderpreferably has a coercive force (Hc) of 125 to 200 kA/m and a saturationmagnetization (σs) of 119 to 167 Am²/kg.

[0117] The ferromagnetic hexagonal ferrite powder includes fine tabularparticles of barium ferrite or strontium ferrite, part of the Fe atomsof which may be displaced with Ti, Co, Ni, Zn, V or the like atoms. Theferromagnetic hexagonal ferrite powder preferably has a tabular diameterof 0.1 μm or less, particularly 10 to 90 nm, especially 10 to 40 nm,with an aspect ratio (diameter/thickness) of 2 to 7, particularly 2 to5, and a BET specific surface area of 30 to 70 m²/g. The ferromagnetichexagonal ferrite powder preferably has a coercive force (Hc) of 135 to260 kA/m and a saturation magnetization (as) of 27 to 72 Am²/kg,particularly 43 to 72 Am²/kg.

[0118] The binder used in the magnetic layer 4 can be selected fromthose useful in the color-containing layer 5 or the backcoating layer 6.For the details, the descriptions given to the color-containing layer 5and the backcoating layer 6 can be referred to. The binder is preferablyused in an amount of 10 to 40 parts by weight, particularly 15 to 25parts by weight, per 100 parts by weight of the ferromagnetic powder.

[0119] The magnetic layer 4 can contain abrasive grains, carbon black,lubricants, hardeners, etc. in addition to the magnetic powder and thebinder.

[0120] Abrasive grains having a Mohs hardness of 7 or higher, such asalumina, silica, ZrO₂, and Cr₂O₃, are used for preference. From thestandpoint of reduction in frictional coefficient and improvement inrunning durability, the abrasive grains preferably have a particle sizeof 0.03 to 0.6 μm, particularly 0.05 to 0.3 μm. The abrasive grains arepreferably added in an amount of 2 to 20 parts by weight, particularly 3to 15 parts by weight, per 100 parts by weight of the ferromagneticpowder.

[0121] The carbon black, lubricants and hardeners to be added to themagnetic layer 4 can be selected from those useful for the formation ofthe color-containing layer 5 or the backcoating layer 6. For the detail,the descriptions given thereto can be referred to here. The carbon blackis preferably used in an amount of 0.1 to 10 parts by weight,particularly 0.1 to 5 parts by weight per 100 parts by weight of theferromagnetic powder. The lubricant is preferably used in an amount of0.5 to 10 parts by weight, particularly 0.5 to 5 parts by weight on thesame basis. The hardener is preferably used in an amount of 2 to 30parts by weight, particularly 5 to 20 parts by weight on the same basis.

[0122] The magnetic layer 4 can further contain various additivescustomarily used in conventional magnetic tape, such as dispersants,rust inhibitors, antifungal agents, and the like.

[0123] The magnetic layer 4 is provided by coating the intermediatelayer 3 with a magnetic coating composition comprising the aforesaidcomponents dispersed in a solvent. The solvent can be chosen from amongthose useful in the color-containing coating composition or thebackcoating composition. The solvent is preferably used in an amount of80 to 500 parts by weight, particularly 100 to 350 parts by weight, per100 parts by weight of the ferromagnetic powder present in the magneticcoating composition.

[0124] The magnetic coating composition is prepared by, for example,preliminarily mixing the ferromagnetic powder and the binder togetherwith a portion of the solvent in a Naughter mixer, etc., kneading thepremixture in a continuous pressure kneader, a twin-screw extruder,etc., diluting the mixture with another portion of the solvent, followedby dispersing in a sand mill, etc., adding to the dispersion additives,such as a lubricant, filtering the dispersion, and adding thereto theremainder of the solvent and a hardener.

[0125] In order to manifest sufficient recording and reproducingcharacteristics, the magnetic layer 4 preferably has a coercive force of119 to 280 kA/m (1495 to 3519 Oe), particularly 120 to 250 kA/m (1508 to3141 Oe), especially 125 to 222 kA/m. The magnetic layer 4 preferablyhas a saturation flux density of 0.1 to 0.5 T, particularly 0.15 to 0.45T.

[0126] For obtaining improved S/N ratio and for preventingself-demagnetization, the thickness of the magnetic layer 4 ispreferably 0.01 to 1 μm, still preferably 0.05 to 0.8 μm, particularlypreferably 0.05 to 0.3 μm.

[0127] The intermediate layer 3 may be either magnetic or nonmagnetic.The magnetic intermediate layer 3 is a layer containing magnetic powder,formed by using a magnetic coating composition mainly comprisingmagnetic powder, nonmagnetic powder, a binder, and a solvent. Thenonmagnetic intermediate layer 3 is a layer formed by using anonmagnetic coating composition mainly comprising nonmagnetic powder, abinder, and a solvent. The coating composition for the intermediatelayer 3, either magnetic or nonmagnetic, will be inclusively referred toas an intermediate layer coating composition.

[0128] The magnetic powder is preferably ferromagnetic powder includinghard magnetic powder and soft magnetic powder.

[0129] The hard magnetic powder includes the ferromagnetic hexagonalferrite powder, ferromagnetic metal powder and ferromagnetic iron oxidepowder which can be used in the magnetic layer 4. For the details ofthese magnetic powders, the descriptions given thereto with respect tothe magnetic layer 4 can apply appropriately.

[0130] The nonmagnetic powder preferably includes particles of inorganicsubstances having a Mohs hardness less than 6. Examples of suchnonmagnetic powder are nonmagnetic iron oxide (red oxide), titaniumoxide, barium sulfate, zinc sulfide, magnesium carbonate, calciumcarbonate, calcium oxide, zinc oxide, magnesium oxide, magnesiumdioxide, tungsten disulfide, molybdenum disulfide, boron nitride, tindioxide, silicon carbide, cerium oxide, corundum, artificial diamond,garnet, siliceous stone, silicon nitride, molybdenum carbide, boroncarbide, tungsten carbide, titanium carbide, diatomaceous earth,dolomite, and resins. In particular, nonmagnetic iron oxide, titaniumoxide, and boron nitride are preferred. These nonmagnetic powders can beused either individually or as a combination of two or more thereof. Thenonmagnetic powder can have any of a spherical shape, a tabular shapeand an acicular shape or may be amorphous. The spherical, tabular oramorphous powder preferably has a particle size of 5 to 200 nm, and theacicular powder preferably has a major axis length of 20 to 300 nm withan acicular ratio of 3 to 20. Where the nonmagnetic powder is used incombination with the magnetic powder, namely, where the intermediatelayer 3 is magnetic, it is preferably used in an amount of 30 to 70parts by weight, particularly 40 to 60 parts by weight, per 100 parts byweight of the magnetic powder. Where the intermediate layer 3 isnonmagnetic, containing no magnetic powder, the amounts of the othercomponents are decided based on 100 parts by weight of the nonmagneticpowder.

[0131] The intermediate layer 3, either magnetic or nonmagnetic,contains a binder and, if desired, abrasive grains, lubricants, carbonblack, hardeners, and the like in addition to the above-mentionedcomponents. These components are the same as described with reference tothe color-containing layer 5, backcoating layer 6 and magnetic layer 4.Preferred amounts of them are shown below, given in terms of parts byweight per 100 parts by weight of the total amount of the magneticpowder and the nonmagnetic powder (in the magnetic intermediate layer 3)or 100 parts by weight of the nonmagnetic powder (in the nonmagneticintermediate layer 3).

[0132] Binder: 8 to 40, particularly 10 to 30

[0133] Abrasive grains: 1 to 30, particularly 1 to 12

[0134] Lubricant: 0.5 to 20, particularly 1 to 7

[0135] Carbon black: 0.5 to 30, particularly 2 to 10

[0136] Hardener: 0.5 to 12, particularly 2 to 8

[0137] If desired, the intermediate layer 3 can contain variousadditives as could be added to the magnetic layer 4.

[0138] The intermediate layer 3 is formed by coating the substrate 2with an intermediate layer coating composition containing the aforesaidvarious components and a solvent. The solvent useful in the intermediatelayer coating composition are the same as those used in thecolor-containing coating composition, backcoating composition andmagnetic coating composition. The solvent is preferably used in anamount of 100 to 700 parts by weight, particularly 300 to 500 parts byweight, per 100 parts by weight of the nonmagnetic powder (in thenonmagnetic intermediate coating composition) or the total of themagnetic powder and the nonmagnetic powder (in the magnetic intermediatelayer coating composition).

[0139] The intermediate layer 3 should have some thickness to assure thecapacity of holding lubricants which is influential on the durability ofthe magnetic tape 1, but too large a thickness is liable to crackinitiation when deflected. A suitable thickness is 0.1 to 3 μm,particularly 0.1 to 2 μm.

[0140] Where the intermediate layer 3 is magnetic, its coercive forcepreferably ranges from 80 to 350 kA/m, particularly 150 to 300 kA/m,from the standpoint of overwrite characteristics and the output balanceover a low to high frequency region. Its saturation flux density ispreferably 0.04 to 0.5 T, particularly 0.05 to 0.4 T, taking the outputbalance over a low to high region into consideration.

[0141] The substrate 2 can be made of any conventional materials knownfor magnetic tape, such as those described in Japanese Patent Laid-OpenNo. 35246/97, column 2, lines 30-42. Of the materials described,nonmagnetic materials such as polyethylene terephthalate (PET),polyethylene naphthalate (PEN), and polyamide are suited. The substrate2 preferably has a thickness of 6 μm or smaller, particularly 5 μm orsmaller, for achieving a high recording capacity. A layer for easyadhesion can be provided on the surface of the substrate 2 for improvingadhesion to other layer.

[0142] The total thickness of the magnetic tape 1 is not greater than 7μm, preferably from 4.5 to 6.8 μm. That is, the magnetic tape of theaforesaid embodiments is of extremely thin type. In general, stiffnessof a magnetic tape decreases with reduction in thickness. It tends tofollow that the contact of the magnetic tape with a magnetic head isreduced, which can result in a reduction of output. Where the magnetictape 1 has a metallic thin layer 7, 8 or 9, which has high stiffness,the magnetic tape has high stiffness despite its small thickness.Therefore, the embodiments in which a metallic thin layer is providedare advantageous in that increase in recording capacity by reduction intotal thickness can be accomplished without involving the problem ofstiffness reduction.

[0143] A preferred method for producing the magnetic tape according tothe present invention is described below taking for instance themagnetic tape 1 of the first embodiment. A magnetic coating compositionfor forming the magnetic layer 4 and an intermediate layer coatingcomposition for forming the intermediate layer 3 are appliedsimultaneously to the substrate 2 in a wet-on-wet coating system to formcoating layers corresponding to the magnetic layer 4 and theintermediate layer 3. That is, the magnetic layer 4 is preferablyprovided while the intermediate layer 3 is wet.

[0144] The coating layers are subjected to magnetic field orientationand dried, and the coated material is wound up. Thereafter, the coatedmaterial is calendered, and a color-containing composition is appliedonto the back side of the substrate 2 to form the color-containing layer5. Alternatively, formation of the intermediate layer 3 and the magneticlayer 4 may be preceded by formation of the color-containing layer 5.The coated material is aged at 40 to 80° C. for 6 to 100 hours and thenslit to a prescribed width to obtain the magnetic tape 1. Before use ofthe magnetic tape 1, a prescribed color-changed pattern 10 providingservo signals is formed on the color-containing layer 5.

[0145] The above-mentioned simultaneous coating technique in awet-on-wet coating system is described, e.g., in Japanese PatentLaid-Open No. 73883/93, column 42, line 31 to column 43, line 31. Thisis a technique in which the magnetic coating composition is appliedbefore the intermediate layer coating composition dries. Where thistechnique is followed, there is obtained magnetic tape which causes fewdropouts and can cope with high-density recording, the coating layers ofwhich have excellent durability.

[0146] The magnetic field orientation treatment is carried out beforeeach coating composition dries. The treatment can be performed byapplying a magnetic field of about 40 kA/m or higher, preferably about80 to 800 kA/m, in parallel with the side coated with the magneticcoating composition or passing the coated material through a solenoidtype magnet of about 80 to 800 kA/m while the magnetic coatingcomposition is wet. By this treatment under such conditions, theferromagnetic powder in the magnetic layer 4 are orientated in thelongitudinal direction of the tape 1. For the purpose of inhibiting thethus orientated ferromagnetic powder from changing its orientationduring the subsequent drying step, it is a preferred manipulation toapply warm air at 30 to 50° C. from above the magnetic layer 4immediately before the magnetic field orientation treatment, whereby thecoated material is dried preliminarily to have a controlled residualsolvent content in each layer.

[0147] The drying of the coating layers is carried out by, for example,supplying gas heated to 30 to 120° C. The degree of drying can becontrolled by adjusting the temperature and the feed rate of the gas.

[0148] The calendering of the coated material is carried out by, forexample, supercalendering comprising passing the coated film between tworolls, such as a combination of a metal roll and a cotton roll or asynthetic resin roll, or a pair of metal rolls. The calendering ispreferably carried out, for example, at a temperature of 60 to 140° C.under a linear pressure of 1 to 5 kN/cm.

[0149] If desired, the surface of the magnetic layer 4 can be subjectedto a finishing step, such as burnishing or cleaning. It is possible toapply the magnetic coating composition and the intermediate layercoating composition by a general successive coating technique.

[0150] While the magnetic tape of the present invention has beendescribed by referring to its preferred embodiments, it should beunderstood that the present invention is not limited thereto, andvarious changes and modifications can be made therein without departingfrom the spirit and scope of the present invention.

[0151] For example, the magnetic tape 1 according to any of theembodiments shown in FIGS. 1, 6, 7, and 9 has a multilayer structurehaving a magnetic layer 4 and an intermediate layer 3 on a substrate 2,the present invention is also applicable to magnetic tape having nointermediate layer as shown in FIGS. 12 through 15.

[0152] While the magnetic tape 1 according to the embodiments shown inFIGS. 1, 6, 12, and 13 achieves servo control by making use oftransmitted light, reflected light may be used for servo control as wellby selecting the materials constituting the color-containing layer 5 orthe backcoating layer 6 so as to have a proper reflectance or refractiveindex, etc.

[0153] The depressions 9′ (servo tracking pattern) made in the metallicthin layer 9 of the fifth embodiment shown in FIG. 10 can be replacedwith a pattern printed on the backcoating layer 6 by various printing orcoating methods such as gravure coating or ink jet printing. In thismodification servo tracking control is carried out by utilizing thedifference in optical properties between the printed pattern and theother region of the side of the non-recording surface.

[0154] Further, the servo tracking pattern in the foregoing embodimentscan be a combination of (a) one or more than one lines having aprescribed width continuously extending in the longitudinal direction ofthe magnetic tape 1 and (b) discontinuous lines having a prescribedwidth arranged along the longitudinal direction of the tape 1. The servotracking pattern may be composed of dots arranged in a line or a curveor a combination thereof. In particular, a pattern composed of acontinuous straight line(s) is advantageous for ease of formation.

[0155] The servo tracking pattern can also be composed of dots (circles,rectangles, triangles, crosses, etc.) or combinations thereof.

[0156] The magnetic tape 1 shown in FIG. 1 or 6 can have a primer layerbetween the substrate 2 and the intermediate layer 3 or thecolor-containing layer 5.

[0157] While the magnetic tape according to the above-describedembodiments is of coated type, the effects of the present invention canbe produced equally when the present invention is applied to magnetictape of metal-deposited type.

[0158] The magnetic tape according to the present invention is suitableas audio visual recording tapes such as a DVC tape, an 8-mm video tape,and a DAT tape, and data storage tapes such as a DLT tape, a DDS tape, a{fraction (1/4)} in. data cartridge tape, and a data 8-mm tape.

[0159] The present invention will now be illustrated in greater detailby way of Examples in view of Comparative Examples for betterunderstanding and for demonstrating its effectiveness, but it should beunderstood that the present invention is not construed as being limitedthereto. In Examples and Comparative Examples, the viscosity of thecolor-containing coating composition prepared was measured with aBrookfield type viscometer at 100 rpm. The viscosity of eachcolor-containing coating composition was adjusted by increasing ordecreasing the amount of the solvent so as to fall within a range of±30% of that of the color-containing coating composition prepared inExample I-1 taken as a standard. Unless otherwise noted, all the partsand percents are given by weight.

EXAMPLE I-1

[0160] The following components except the hardener were kneaded in akneader, dispersed in a stirrer, and further finely dispersed in a sandmill. The dispersion was filtered through a 1 μm filer, and finally, thehardener was added thereto to prepare a color-containing coatingcomposition, a magnetic coating composition, and an intermediate layercoating composition having the respective formulations described below.Formulation of Color-Containing Coating Composition: ITO (averageparticle size: 35 nm) 100 parts Silicone particles (average particlesize: 3 parts 0.5 μm; “TOSPEARL 105”, produced by TOSHIBA SILICONE Co.,Ltd.) Phosphoric ester (lubricant; “PHOSPHANOL 3 parts RE610”, producedby TOHO CHEMICAL INDUSTRY Co., Ltd.) 3,3'-Dipropylthiadicarbocyanineiodide (coloring matter) 0.3 part Polyurethane resin (binder; numberaverage 28 parts molecular weight: 25,000; sulfoxyl group content: 1.2 ×10⁻⁴ mol/g; Tg: 45° C.) Stearic acid (lubricant) 0.5 part Polyisocyanate(hardener; “CORONATE L”, produced by 4 parts NIPPON POLYURETHANEINDUSTRY Co., Ltd.; solid content: 75%) Methyl ethyl ketone (solvent;hereinafter 120 parts abbreviated as MEK) Toluene (solvent) 80 partsCyclohexanone (solvent) 40 parts Formulation of Magnetic CoatingComposition: Acicular ferromagnetic metal powder 100 parts consistingmainly of Fe (Fe:Co:Al:Y:Ba = 70:25:2:2:1 (by weight); major axislength: 0.07 μm; acicular ratio: 5; BET specific surface area: 56 m²/g;X-ray particle size: 0.014 μm; coercive force: 160 kA/m (2010 Oe);saturation magnetization: 142 Am²/kg) Alumina (abrasive; average primary8 parts particle size: 0.15 μm) Carbon black (average primary particle0.5 parts size: 0.018 μm) Vinyl chloride copolymer (binder; average 10parts degree of polymerization: 280; epoxy content: 1.2%; sulfoxylcontent: 8 × 10⁻⁵ mol/g) Polyurethane resin (binder; number average 7parts molecular weight: 25000; sulfoxyl content: 1.2 × 10⁻⁴ mol/g; Tg:45° C.) Stearic acid (lubricant) 1.5 parts 2-Ethylhexyl oleate(lubricant) 2 parts Polyisocyanate (hardener; “CORONATE L”, produced by5 parts NIPPON POLYURETHANE INDUSTRY Co., Ltd.; solids content: 75%) MEK(solvent) 120 parts Toluene (solvent) 80 parts Cyclohexanone (solvent)40 parts Formulation of Intermediate Layer Coating Composition: Acicularα-Fe₂O₃ (average particle size 100 parts (major axis length): 0.12 μm;acicular ratio: 10; BET specific surface area: 48 m²/g) Alumina(abrasive; average primary 3 parts particle size: 0.15 μm) Vinylchloride copolymer (binder; average 12 parts degree of polymerization:280; epoxy content: 1.2%; sulfoxyl content: 8 × 10⁻⁵ mol/g) Polyurethaneresin (binder; number average 8 parts molecular weight: 25000; sulfoxylcontent: 1.2 × 10⁻⁴ mol/g; Tg: 45° C.) Stearic acid (lubricant) 1 part2-Ethylhexyl oleate (lubricant) 4 parts Polyisocyanate (hardener;“CORONATE L”, produced by 4 parts NIPPON POLYURETHANE INDUSTRY Co.,Ltd.; solids content: 75%) MEK (solvent) 90 parts Toluene (solvent) 60parts Cyclohexanone (solvent) 30 parts

[0161] The intermediate layer coating composition and the magneticcoating composition were applied simultaneously onto a 4.5 μm thick PENfilm by means of a die coater to form the respective coating layershaving a dry thickness of 1.5 μm and 0.2 μm, respectively. The coatedfilm was passed through a solenoid type magnet of 400 kA/m while wet anddried in a drying oven by applying hot air at 80° C. at a rate of 10m/min. The coated film was then calendered to form an intermediate layerand a magnetic layer. The reverse side of the substrate was coated withthe color-containing coating composition and dried at 90° C. to form acolor-containing layer having a thickness of 1.0 μm. The coated film wasslit into strips of 12.7 mm in width to obtain a magnetic tape havingthe layer structure shown in FIG. 1. The resulting magnetic tape had acoercive force of 165 kA/m (2073 Oe), a saturation flux density of 0.37T, and a squareness ratio of 0.86. The surface of the magnetic layer hadan arithmetic mean roughness Ra of 4.3 nm and a 10 point heightparameter Rz of 41 nm.

[0162] As shown in FIG. 2, the color-containing layer of the resultingmagnetic tape was irradiated with laser beams each having a diameter of2 μm, a wavelength of 1020 nm, and an output power of 50 mW to form acolor-changed pattern affording servo signals which was comprised ofparallel straight lines extending in the longitudinal direction andequally spaced in the width direction of the magnetic tape.

EXAMPLE I-2

[0163] A magnetic tape was obtained in the same manner as in ExampleI-1, except for changing the amounts of ITO and the coloring matter inthe color-containing coating composition to 70 parts and 0.6 part,respectively, and adding 30 parts of spherical magnetite particleshaving an average particle size of 80 nm to the color-containing coatingcomposition. A color-changed pattern was formed on the color-containinglayer in the same manner as in Example I-1.

EXAMPLE I-3

[0164] A magnetic tape was obtained in the same manner as in ExampleI-1, except that the silicone particles were not used in thecolor-containing layer. A color-changed pattern was formed on thecolor-containing layer in the same manner as in Example I-1.

EXAMPLE I-4

[0165] A magnetic tape was obtained in the same manner as in ExampleI-1, except that the coloring matter used in the color-containingcoating composition was replaced with Crystal Violet. A color-changedpattern was formed on the color-containing layer in the same manner asin Example I-1.

EXAMPLE I-5

[0166] A magnetic tape was obtained in the same manner as in ExampleI-1, except that the coloring matter used in the color-containingcoating composition was replaced with Thionine. A color-changed patternwas formed on the color-containing layer in the same manner as inExample I-1.

EXAMPLE I-6

[0167] A magnetic tape was obtained in the same manner as in ExampleI-1, except for changing the amount of ITO in the color-containingcoating composition to 50 parts and adding 50 parts of TiO₂ particleshaving an average particle size of 30 nm to the color-containing coatingcomposition. A color-changed pattern was formed on the color-containinglayer in the same manner as in Example I-1.

EXAMPLE I-7

[0168] A magnetic tape was obtained in the same manner as in ExampleI-1, except for changing the amount of the silicone particles used inthe color-containing coating composition to 6 parts. A color-changedpattern was formed on the color-containing layer in the same manner asin Example I-1.

EXAMPLE I-8

[0169] A magnetic tape was obtained in the same manner as in ExampleI-1, except for changing the amount of ITO in the color-containingcoating composition to 10 parts and adding 90 parts of sphericalparticles of α-Fe₂O₃ having an average particle size of 20 nm to thecolor-containing coating composition. A color-changed pattern was formedon the color-containing layer in the same manner as in Example I-1.

COMPARATIVE EXAMPLE I-1

[0170] A magnetic tape was obtained in the same manner as in ExampleI-1, except for using no coloring matter in the color-containing coatingcomposition.

COMPARATIVE EXAMPLE I-2

[0171] A magnetic tape was obtained in the same manner as in ExampleI-1, except for replacing the color-containing coating composition witha backcoating composition having the following formulation. Formulationof Backcoating Composition: Carbon black (antistatic agent; average 40parts primary particle size: 0.018 μm) NIPPORAN 2301 (binder;polyurethane 50 parts produced by NIPPON POLYURETHANE INDUSTRY Co.,Ltd.; solids content: 40%) Polyisocyanate (hardener; “CORONATE L”, 4parts produced by NIPPON POLYURETHANE INDUSTRY Co., Ltd.; solidscontent: 75%) Nitrocellulose 20 parts Stearic acid (lubricant) 1 partMEK (solvent) 140 parts Toluene (solvent) 140 parts Cyclohexanone(solvent) 140 parts

[0172] In order to evaluate the performance of the magnetic tapesobtained in Examples and Comparative Examples, the reproduction outputand light transmission of the magnetic tape and the coefficient ofdynamic friction, surface resistivity, and color changeability of thecolor-containing layer were measured as follows. Further, a servotracking test was carried out on the magnetic tapes in accordance withthe following test method. The results obtained are shown in Table 1below.

[0173] 1) Reproduction Output

[0174] Signals having a recording wavelength of 0.6 μm were recorded,and the reproduction output was measured in accordance with a headtester method. The results obtained were expressed relatively taking theoutput of Comparative Example 1 as a standard (0 dB).

[0175] 2) Light Transmission

[0176] The magnetic tape was irradiated with monochromatic light havingthe wavelength used for servo signal reading, and the percent lighttransmission in terms of the ratio of transmitted light intensity toincident light intensity was obtained. The values shown in Table 1 aretransmissions measured before the color-changed pattern giving the servoinformation is formed on the color-containing layer.

[0177] 3) Coefficient of Dynamic Friction

[0178] The magnetic tape was run on a tape running tester TBT-300Dmanufactured by YOKOHAAMA SYSTEM KENKYUSHO K.K. at a speed of 3.36cm/sec with its color-containing layer in contact with a cylinder havinga diameter of 5 mm at 180°. The tensions on the reel-off side and thereel-up side were measured to obtain a frictional coefficient (p) fromequation (iii): $\begin{matrix}{\mu = {\frac{1}{\pi}\ln \frac{{reel}\text{-}{off}\quad {tension}}{{reel}\text{-}{up}\quad {tension}}}} & \text{(iii)}\end{matrix}$

[0179] 4) Surface Resistivity

[0180] A pair of electrodes plated with 24-carat gold and finished tohave a surface roughness of N4 (see ISO 1302) and having a radius of 10mm were put in parallel horizontally on the color-containing layer of atest piece of the magnetic tape with a center-to-center distance d=12.7mm. A direct voltage of 1100 V±10 V was passed through the electrodeswhile applying a force of 0.25 N to both ends of the test piece, and thecurrent between the electrodes was measured, from which the surfaceresistivity was obtained.

[0181] 5) Color Change

[0182] The color-containing layer of the magnetic tape was irradiatedwith a laser beam, and the irradiated part was observed under an opticalmicroscope to confirm discoloration.

[0183] 6) Servo Tracking Test

[0184] Signals were recorded on the magnetic layer of the magnetic tapewhile carrying out servo tracking in accordance with push-pull methodusing transmitted light to evaluate the track controllability. The servosignals were detected with light having the same wavelength as that usedfor the above measurement of light transmission. Detection was performedby converting the difference in light transmission between a discoloredpart and a non-discolored part of the color-containing layer intoelectrical signals.

[0185] Further, the recorded signals were reproduced to measure theoutputs by a head tester method and to measure the envelopecharacteristics. The outputs were expressed relatively taking the resultof Example 1 as a standard (O dB). The envelope characteristics weregraded based on the following standard.

[0186] A . . . The output level was constant over the whole length of atrack, depicting a uniform envelope.

[0187] B . . . The output level decreased in some parts in the formerhalf or the latter half of a track, displaying a distorted envelope.TABLE 1 Magnetic Tape Color-Containing Layer Servo Signal DetectionDynamic Surface Servo Tracking Test Reproduction Wavelength TransmissionFrictional Resistivity Color Reproduction Output (dB) (nm) (%)Coefficient (Ω/□) Change Controllability Output (dB) Envelope ExampleI-1 +0.2 650 16 0.23 3.4 × 10⁷ observed controllable 0 (reference) A I-2+0.4 650 8 0.19 8.3 × 10⁷ observed controllable −0.4 B I-3 +0.2 650 160.42 3.6 × 10⁷ observed controllable −0.5 B I-4 +0.2 635 14 0.21 2.8 ×10⁷ observed controllable +0.1 A I-5 +0.4 650 12 0.22 5.2 × 10⁷ observedcontrollable −0.2 A I-6 +0.2 650 18 0.20 1.8 × 10⁸ observed controllable+0.2 A I-7 +0.1 650 16 0.12 6.6 × 10⁷ observed controllable +0.3 A I-8+0.3 650 17 0.18  7.8 × 10¹¹ observed controllable −0.2 B Compara. I-1 0(reference) 650 21 0.21 3.8 × 10⁷ not observed uncontrollable — —Example I-2 +0.2 650 0.4 0.18 5.1 × 10⁵ not observed uncontrollable — —

[0188] As is apparent from the results in Table 1, the magnetic tapesaccording to the present invention prepared in Examples I-1 to I-8provide high reproduction outputs and achieve satisfactory servocontrol. In particular, the magnetic tapes of Examples achieved reliableservo control even when the tapes were recorded on 600 data tracks.Further, the magnetic tapes of Examples had a low dynamic frictionalcoefficient and a low surface resistivity, proving that thecolor-containing layer also functions as a backcoating layer. While notshown in Table 1, the color-containing layer of the magnetic tapes ofExamples was equal to a backcoating layer of ordinary magnetic tapes inarithmetic mean roughness and 10 point height parameter.

EXAMPLE II-1

[0189] The following components except the hardener were kneaded in akneader, dispersed in a stirrer, and further finely dispersed in a sandmill. The dispersion was filtered through a 1 μm filer, and finally, thehardener was added thereto to prepare a color-containing coatingcomposition, a magnetic coating composition, and an intermediate layercoating composition having the respective compositions described below.Formulation of Color-Containing Coating Composition: ITO (averageparticle size: 35 nm) 100 parts Silicone particles (average particlesize: 3 parts 0.5 μm; “TOSPEARL 105”, produced by TOSHIBA SILICONE Co.,Ltd.) Phosphoric ester (lubricant; “PHOSPHANOL 3 parts RE610”, producedby TOHO CHEMICAL INDUSTRY Co., Ltd.) 3,3'-Dipropylthiadicarbocyanineiodide (coloring matter) 0.2 part Polyurethane resin (binder; numberaverage 28 parts molecular weight: 25,000; sulfoxyl group content: 1.2 ×10⁻⁴ mol/g; Tg: 45° C.) Stearic acid (lubricant) 0.5 part Polyisocyanate(hardener; “CORONATE L”, produced by 4 parts NIPPON POLYURETHANEINDUSTRY Co., Ltd.; solid content: 75%) MEK (solvent) 120 parts Toluene(solvent) 80 parts Cyclohexanone (solvent) 40 parts Formulation ofMagnetic Coating Composition: Acicular ferromagnetic metal powder 100parts consisting mainly of Fe (Fe:Co:Al:Y:Ba = 83:10:4:2:1 (by weight);major axis length: 0.07 pm; acicular ratio: 7; BET specific surfacearea: 56 m²/g; X-ray particle size: 0.013 μm; coercive force: 160 kA/m(1822 Oe); saturation magnetization: 145 Am²/kg) Alumina (abrasive;average 9 parts particle size: 0.15 μm) Carbon black (average primaryparticle 0.3 parts size: 0.05 μm) Vinyl chloride copolymer (binder;average 6 parts degree of polymerization: 280; epoxy content: 1.2%;sulfoxyl content: 8 × 10⁻⁵ mol/g) Polyurethane resin (binder; numberaverage 7 parts molecular weight: 25000; sulfoxyl content: 1.2 × 10⁻⁴mol/g; Tg: 45° C.) Stearic acid (lubricant) 1 parts 2-Ethylhexyl oleate(lubricant) 2 parts Polyisocyanate (hardener; “CORONATE L”, produced by4 parts NIPPON POLYURETHANE INDUSTRY Co., Ltd.) MEK (solvent) 120 partsToluene (solvent) 80 parts Cyclohexanone (solvent) 40 parts Formulationof Intermediate Layer Coating Composition: Acicular α-Fe₂O₃ (averageparticle size 100 parts (major axis length): 0.12 μm; acicular ratio:10; BET specific surface area: 48 m²/g) Alumina (abrasive; averageprimary 3 parts particle size: 0.15 μm) Vinyl chloride copolymer(binder; average 12 parts degree of polymerization: 280; epoxy content:1.2%; sulfoxyl content: 8 × 10⁻⁵ mol/g) Polyurethane resin (binder;number average 8 parts molecular weight: 25000; sulfoxyl content: 1.2 ×10⁻⁴ mol/g; Tg: 45° C.) Stearic acid (lubricant) 1 part 2-Ethylhexyloleate (lubricant) 4 parts Polyisocyanate (hardener; “CORONATE L”,produced by 4 parts NIPPON POLYURETHANE INDUSTRY Co., Ltd.) MEK(solvent) 90 parts Toluene (solvent) 60 parts Cyclohexanone (solvent) 30parts

[0190] A thin film of Au was deposited on both sides of a 4.5 μm thickPEN film by vacuum thin film processing to a deposit thickness of 0.05μm/side to prepare a substrate. The intermediate layer coatingcomposition and the magnetic coating composition were appliedsimultaneously onto one of the metallic thin films by means of a diecoater to form the respective coating layers having a dry thickness of1.5 μm and 0.2 μm, respectively. The coated film was passed through asolenoid type magnet of 400 kA/m while wet and dried in a drying oven byapplying hot air at 80° C. at a rate of 10 m/min. The coated film wasthen calendered to form an intermediate layer and a magnetic layer. Theother metallic thin film of the substrate was coated with thecolor-containing coating composition and dried at 90° C. to form acolor-containing layer having a thickness of 1.0 μm. The coated film wasslit into strips of 12.7 mm in width to obtain a magnetic tape havingthe layer structure shown in FIG. 7. The resulting magnetic tape had acoercive force of 151 kA/m (1898 Oe), a saturation flux density of 0.36T, and a squareness ratio of 0.90. The surface of the magnetic layer hadan arithmetic mean roughness Ra of 4.6 nm and a 10 point heightparameter Rz of 55 nm.

[0191] The color-containing layer of the resulting magnetic tape wasirradiated with laser beams each having a diameter of 2 μm, a wavelengthof 1020 nm, and an output power of 50 mW to form a color-changed patternaffording servo signals which comprised parallel straight linesextending in the longitudinal direction and equally spaced in the widthdirection of the tape.

EXAMPLE II-2

[0192] A magnetic tape was obtained in the same manner as in ExampleII-1, except that the silicone particles were not used in thecolor-containing layer. A color-changed pattern was formed on thecolor-containing layer in the same manner as in Example II-1.

EXAMPLE II-3

[0193] A magnetic tape was obtained in the same manner as in ExampleII-1, except that the coloring matter used in the color-containingcoating composition was replaced with Crystal Violet. A color-changedpattern was formed on the color-containing layer in the same manner asin Example II-1.

EXAMPLE II-4

[0194] A magnetic tape was obtained in the same manner as in ExampleII-1, except that the coloring matter used in the color-containingcoating composition was replaced with Thionine. A color-changed patternwas formed on the color-containing layer in the same manner as inExample II-1.

EXAMPLE II-5

[0195] A magnetic tape was obtained in the same manner as in ExampleII-1, except for changing the amount of ITO in the color-containingcoating composition to 80 parts and adding 20 parts of TiO₂ particleshaving an average particle size of 40 nm to the color-containing coatingcomposition. A color-changed pattern was formed on the color-containinglayer in the same manner as in Example II-1.

EXAMPLE II-6

[0196] A magnetic tape was obtained in the same manner as in ExampleII-1, except for changing the amount of the silicone particles used inthe color-containing coating composition to 6 parts. A color-changedpattern was formed on the color-containing layer in the same manner asin Example II-1.

EXAMPLE II-7

[0197] A magnetic tape was obtained in the same manner as in ExampleII-1 with the following exceptions. A metallic thin layer of Al having athickness of 0.03 μm was formed on the PEN film by vacuum deposition,and a metallic thin layer 8 was not formed. The metallic thin layer 7was coated with a color-containing coating composition and a backcoatingcomposition having the following respective formulations simultaneouslyin a wet-on-wet system in this order to form a color-containing layerhaving a thickness of 0.15 μm and a backcoating layer having a thicknessof 0.35 μm as an outermost layer. The color-containing layer of theresulting magnetic tape was irradiated with laser beams each having adiameter of 3 μm, a wavelength of 680 nm, and an output power of 20 mWto form a color-changed pattern similar to that of Example II-1.Formulation of Color-Containing Composition ITO (average particle size:35 nm) 100 parts Cyanine dye (formula (1) wherein R₁ and 6 parts R₂ areeach C₄H₉; n is 2; and X is a perchlorate ion) Polyurethane resin(binder; number average 28 parts molecular weight: 25,000; sulfoxylgroup content: 1.2 × 10⁻⁴ mol/g; Tg: 45° C.) Polyisocyanate (hardener;“CORONATE L”, produced by 4 parts NIPPON POLYURETHANE INDUSTRY Co.,Ltd.; solids content: 75%) MEK (solvent) 120 parts Toluene (solvent) 80parts Cyclohexanone (solvent) 40 parts Formulation of BackcoatingComposition ITO (average particle size: 35 nm) 100 parts Silicone resin(average particle size: 1 part 0.5 μm; TOSPEARL 105, produced by TOSHIBASILICONE Co., Ltd.) Phosphoric ester (lubricant; “Phosphanol 3 partsRE610”, produced by Toho Chemical Industry Co., Ltd.) Polyurethane resin(binder; number average 28 parts molecular weight: 25,000; sulfoxylgroup content: 1.2 × 10⁻⁴ mol/g; Tg: 45° C.) Stearic acid (lubricant)0.5 part Polyisocyanate (hardener; “CORONATE L”, produced by 4 partsNIPPON POLYURETHANE INDUSTRY Co., Ltd.; solids content: 75%) MEK(solvent) 120 parts Toluene (solvent) 80 parts Cyclohexanone (solvent)40 parts

COMPARATIVE EXAMPLE II-1

[0198] A magnetic tape was obtained in the same manner as in ExampleII-1, except for excluding the dye from the color-containing coatingcomposition.

COMPARATIVE EXAMPLE II-2

[0199] A magnetic tape was obtained in the same manner as in ExampleII-1, except for replacing the color-containing coating composition usedin Example II-1 with a backcoating composition having the followingformulation. Formulation of Backcoating Composition Carbon black(antistatic agent; average 40 parts primary particle size: 0.018 μm)NIPPON 2301 (binder; polyurethane 50 parts produced by NIPPONPOLYURETHANE INDUSTRY Co., Ltd.; solid content: 40%) Polyisocyanate(hardener; “CORONATE L”, 4 parts produced by NIPPON POLYURETHANEINDUSTRY Co., Ltd.; solids content: 75%) Nitrocellulose 20 parts Stearicacid (lubricant) 1 part MEK (solvent) 140 parts Toluene (solvent) 140parts Cyclohexanone (solvent) 140 parts

[0200] The performance of the magnetic tapes prepared in Examples II-1to II-7 and Comparative Examples II-1 to II-2 was evaluated in terms ofreproduction output of the magnetic tape, coefficient of dynamicfriction and surface resistivity of the color-containing layer, andcolor changeability of the color-containing layer in the same manner asdescribed above. Further, the magnetic tapes were subjected to the servotracking test. Additionally, the light reflectance of thecolor-containing layer side was measured as follows. The resultsobtained are shown in Table 2 below.

[0201] Light Reflectance:

[0202] The color-containing layer side of the magnetic tape wasirradiated with monochromatic light of the wavelength used for servesignal reading to obtain a percent light reflectance in terms of theratio of reflected light intensity to incident light intensity. Thevalues shown in Table 2 are reflectances measured before thecolor-changed pattern giving the servo information was formed on thecolor-containing layer. TABLE 2 Magnetic Tape Color-containing LayerServo Signal Detection Dynamic Surface Servo Tracking Test ReproductionWavelength Reflectance Frictional Resistivity Color Reproduction Output(dB) (nm) (%) Coefficient (Ω/□) Chage Controllability Output (dB)Envelope II-1 +0.1 650 35 0.20 <1 × 10⁴ observed controllable 0(reference) A Example II-2 +0.0 650 36 0.43 <1 × 10⁴ observedcontrollable −0.4 B II-3 +0.2 635 32 0.19 <1 × 10⁴ observed controllable+0.2 A II-4 +0.3 650 31 0.16 <1 × 10⁴ observed controllable −0.1 A II-5+0.3 650 27 0.18 <1 × 10⁴ observed controllable +0.2 A II-6 +0.1 650 310.11 <1 × 10⁴ observed controllable −0.2 B II-7 +0.3 680 38 0.18 <1 ×10⁴ observed controllable +0.3 A Compara. II-1 0 (reference) 650 42 0.22<1 × 10⁴ not observed uncontrollable — — Example II-2 −0.1 650 <0.1 0.17<1 × 10⁴ not observed uncontrollable — —

[0203] As is apparent from the results in Table 2, the magnetic tapesaccording to the present invention prepared in Examples II-1 to II-7provide high reproduction outputs and achieve satisfactory servo controlsimilarly to those of Examples I-1 to I-8. In particular, it wasconfirmed that the magnetic tapes of Examples II-1 to II-7 achievedreliable servo control even when the tapes were recorded on 600 tracks.Further, the magnetic tapes of Examples II-1 to II-6 had a low dynamicfrictional coefficient and a low surface resistivity, proving that thecolor-containing layer sufficiently performs the functions as abackcoating layer. While not shown in Table 2, the color-containinglayer of the magnetic tapes of Examples II-1 to II-6 and the backcoatinglayer of the magnetic tape of Example II-7 were equal to a backcoatinglayer of ordinary magnetic tapes in arithmetic mean roughness and 10point height parameter.

EXAMPLE III-1

[0204] The following components except the hardener were kneaded in akneader, dispersed in a stirrer, and further finely dispersed in a sandmill. The dispersion was filtered through a 1 μm filer, and finally, thehardener was added thereto to prepare a backcoating composition A, amagnetic coating composition, and an intermediate layer coatingcomposition having the respective compositions described below.Formulation of Backcoating Composition A Acicular α-Fe₂O₃ (major axislength: 0.12 μm) 100 parts Silicone resin particles (average particle 3parts size: 0.5 μm) Phosphoric ester (lubricant) 3 partsSulfoxyl-containing polyurethane resin (binder) 28 parts Stearic acid(lubricant) 0.5 part Polyisocyanate compound (hardener; solids content:75%) 4 parts MEK (solvent) 120 parts Toluene (solvent) 80 partsCyclohexanone (solvent) 40 parts Formulation of Magnetic CoatingComposition Acicular ferromagnetic metal powder 100 parts consistingmainly of iron (major axis length: 80 nm; coercive force: 183 kA/m;saturation magnetization: 145 Am²/g; BET specific surface area: 55 m²/g)Sulfoxyl-containing vinyl chloride copolymer (binder) 10 partsSulfoxyl-containing polyurethane resin (binder) 10 parts Carbon black(average particle size: 30 nm) 0.5 part α-Alumina (abrasive; averageparticle size: 200 nm) 10 parts Myristic acid (lubricant) 2 parts Butylstearate (lubricant) 0.5 part Isocyanate compound (hardener; solidscontent: 75%) 2 parts MEK (solvent) 250 parts Cyclohexanone (solvent)100 parts Formulation of Intermediate Layer Coating Composition Acicularα-Fe₂O₃ (major axis length: 150 nm) 100 parts Sulfoxyl-containing vinylchloride copolymer (binder) 10 parts Sulfoxyl-containing polyurethaneresin (binder) 15 parts α-Alumina (abrasive; average particle size: 200nm) 3 parts Carbon black (average particle size: 20 nm) 5 parts Myristicacid (lubricant) 2 parts Butyl stearate (lubricant) 2 parts Isocyanatecompound (hardener; solids content: 75%) 5 parts MEK (solvent) 150 partsCyclohexanone (solvent) 50 parts

[0205] Indium was deposited on one side of a 4.5 μm thick PET film as asubstrate 2 by vacuum evaporation to a deposit thickness of 20 nm toform a metallic thin layer 9. The backcoating composition A was appliedto the metallic thin layer 9 and dried at 90° C. to form a backcoatinglayer 6 having a thickness of 0.5 μm. On the opposite side of thesubstrate 2 were applied the intermediate coating composition and themagnetic coating composition simultaneously by means of a die coater toform the respective coating layers having a dry thickness of 1.5 μm and0.2 μm, respectively. The coated film was passed through a solenoid typemagnet of 400 kA/m while wet and dried in a drying oven by applying hotair at 80° C. at a rate of 10 m/min. The coated film was then calenderedto form an intermediate layer 3 and a magnetic layer 4. The coated filmwas slit into strips of 12.7 mm in width to obtain a magnetic tape. Alaser beam having a diameter of 1 μm, a wavelength of 780 nm, and anoutput power of 4 mW was intermittently cast on the backcoating layerside of the magnetic tape. The irradiated indium of the metallic thinlayer 9 fused to form depressions 9′ (servo tracking pattern) 1 μm wide,2 μm long and 20 nm deep at regular intervals in the longitudinaldirection of the tape as shown in FIG. 11. The distance between adjacentdepressions 9′ was 2 μm.

EXAMPLE III-2

[0206] A magnetic tape was obtained in the same manner as in ExampleIII-1, except for replacing the backcoating composition A with abackcoating composition B having the following formulation. Formulationof Backcoating Composition B Carbon black (average particle size: 18 nm)5 parts Mn-hematite (average particle size: 100 nm) 25 partsPolyurethane resin (binder) 50 parts Nitrocellulose (binder) 30 partsIsocyanate compound (hardener; solids content: 75%) 18 parts Copperphthalocyanine 5 parts Stearic acid (lubricant) 1 part MEK (solvent) 150parts Toluene (solvent) 150 parts Cyclohexanone (solvent) 150 parts

[0207] Signals were recorded on the magnetic layer of the magnetic tapeobtained in Examples III-1 and 2 while carrying out servo tracking inaccordance with push-pull method. For servo signal reading, thebackcoating layer was irradiated with light having a wavelength of 780nm, and the reflected light intensity was detected. As a result, themagnetic tapes achieved reliable servo control even when the tapes wererecorded on 600 tracks as shown in Table 3 below. In particular, themagnetic tape of Example III-1, in which the backcoating layer did notcontain carbon black, showed a higher reflectance on its backcoatinglayer side, making the servo control more reliable. After each magnetictape was stored for 3 months as wound around a reel, the surfacecondition of the magnetic layer 4 was observed. As shown in Table 3, itwas confirmed that the surface condition was maintained on the levelbefore storage, proving that a change in surface condition, if any, ofthe backcoating layer 6 which might be caused by the depressions 9′ wasnot transferred onto the magnetic layer 4 during storage. Additionally,while not shown in Table 3, each tape was proved to maintain theperformance in terms of reproduction output and dropout ratio on thelevel of ordinary magnetic tapes. TABLE 3 Track Adverse Reflectance (%)Difference of Example Control- Influence on Other Reflectance No.lability Magnetic Layer Pattern Region (%) III-1 good none 5 30 83 III-2acceptable none 3 10 70

[0208] This application claims the priority of Japanese PatentApplication No. 9-337733 filed Nov. 21, 1997, Japanese PatentApplication No. 10-190867 filed Jul. 6, 1998 and Japanese PatentApplication No. 10-215432 filed Jul. 30, 1998, which are incorporatedherein by reference.

1. A magnetic tape comprising a substrate having on one side thereof amagnetic layer serving as a recording surface and on the other sidethereof a resin layer serving as a non-recording surface, wherein saidmagnetic tape has a region on the side of the non-recording surfacealong the longitudinal direction of the tape in which a regular patternfor servo tracking having different optical properties from the othermajor region of the side of the non-recording surface is to be formed,and said magnetic tape has a thickness of 7 μm or less.
 2. The magnetictape according to claim 1, wherein said optical properties are areflectance or a transmission of light, and the difference between saidpattern and the other major region of the non-recording surface inreflectance or transmission of light having a prescribed wavelength usedfor servo tracking is 10% or more.
 3. The magnetic tape according toclaim 1, wherein said magnetic tape has on the side of the non-recordingsurface a layer containing a coloring matter and capable of opticallyrecording servo signals for tracking.
 4. The magnetic tape according toclaim 2, wherein said layer containing a coloring matter has beenirradiated with light having a prescribed wavelength from the side ofthe non-recording surface to change the color of said coloring matterthereby to form a color-changed pattern of prescribed shape providingservo signals for tracking.
 5. The magnetic tape according to claim 1,wherein said magnetic tape has a coefficient of dynamic friction of 0.15to 0.35 on the non-recording surface thereof.
 6. The magnetic tapeaccording to claim 3, wherein said magnetic tape further comprises abackcoating layer serving as an outermost layer contains a binder andinorganic powder and is located on said layer containing a coloringmatter.
 7. The magnetic tape according to claim 4, wherein said magnetictape further comprises a metallic thin layer located between saidsubstrate and said layer containing a coloring matter so that said servosignals are to be read by irradiating said color-changed pattern withlight having a prescribed wavelength from the side of the non-recordingsurface and then detecting the intensity of light reflected on saidmetallic thin layer.
 8. The magnetic tape according to claim 1, whereinsaid magnetic tape further comprises a thin layer of a metal or an alloyhaving a low melting point which is located between said substrate andsaid resin layer, and a servo tracking pattern comprising depressions isformed in said thin layer.
 9. The magnetic tape according to claim 8,wherein said servo tracking pattern has a width of 0.1 to 30 μm and adepth of from {fraction (1/3)} of the thickness of said thin layer up tothe whole thickness of said thin layer.
 10. A magnetic tape comprising asubstrate having on one side thereof a magnetic layer serving as arecording surface and on the other side thereof a resin layer serving asa non-recording surface, wherein said magnetic tape has a regularpattern for servo tracking on the side of the non-recording surfacealong the longitudinal direction of the tape which has different opticalproperties from the other major region of the side of the non-recordingsurface, and said magnetic tape has a thickness of 7 μm or less.